Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins

The use of cobalt dinitrosoalkane complexes in the C-H functionalization of alkenes has been demonstrated. Reaction of a series of alkenes with Me4CpCo(CO)2 in the presence of NO generatesintermediate cobalt dinitrosoalkane complexes that can be deprotonated α to the nitrosyl group and added to various Michael acceptors. The resultant products can then undergo retrocycloaddition reactions in the presence of the original alkene to regenerate the starting cobalt dinitrosoalkane complex and release the functionalized alkene. Copyright © 2008 American Chemical Society.